| Levante | 0 - 5 | Barcelona |
| |
| Neymar da Silva Santos Júnior (34)
Ivan Rakitic (44)
Sandro Ramírez (57)
Pedro Rodríguez Ledesma (64)
Lionel Messi (77) |
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| Ciutat de València |
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| 21 September |
| |
| Córdoba | 1 - 3 | Sevilla |
| Borja García Freire (83) |
| Carlos Bacca (8)
Stéphane Mbia (72)
Carlos Bacca (pen 88) |
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| Estadio Nuevo Arcángel |
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| 21 September |
| |
| Villarreal | 4 - 2 | Rayo Vallecano |
Javier Espinosa (33)
Mateo Musacchio (62)
Luciano Vietto (74)
Luciano Vietto (87) |
| Gael Kakuta (22)
Alberto Bueno (29) |
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| El Madrigal |
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| 21 September |
| |
| Real Sociedad | 1 - 2 | Almería |
| Gonzalo Castro (85) |
| Alberto De la Bella (og 30)
Mauro Dos Santos (51) |
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| Anoeta |
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| 20 September |
| |
| Espanyol | 2 - 2 | Málaga |
Felipe Caicedo (16)
Christian Stuani (88) |
| Ignacio Camacho (53)
Sergio Paulo Barbosa Valente (93) |
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| Power8 Stadium |
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| 20 September |
| |
| Atlético de Madrid | 2 - 2 | Celta de Vigo |
João Miranda De Souza Filho (31)
Diego Godín (41) |
| Pablo Hernández (19)
Manuel Agudo Durán (pen 53) |
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| Vicente Calderón |
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| 20 September |
| |
| Athletic Club | 0 - 1 | Granada CF |
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| San Mamés |
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| 20 September |
| |
| Deportivo de La Coruña | 2 - 8 | Real Madrid |
Haris Medunjanin (pen 51)
José Verdú Nicolás (84) |
| Cristiano Ronaldo (29)
James Rodríguez (36)
Cristiano Ronaldo (41)
Gareth Bale (66)
Gareth Bale (74)
Cristiano Ronaldo (78)
Javier Hernández (88)
Javier Hernández (92) |
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| Municipal de Riazor |
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| 19 September |
| |
| Elche | 0 - 2 | Eibar |
| |
| Daniel García Carrillo (3)
Raúl Albentosa (42) |
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| Martínez Valero |
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